This is a way of repairing permissions to write to the SD card android kitkat including Samsung S5 
Just to root device 
- Make sure that you have root access 
- Use the file manager [Explorer
root enabled and enter /system/etc/permissions/ 
- Edit platform.xml, search "WRITE_EXTERNAL_STORAGE" and add <group gid="media_rw"/> 
- Save and restart 
Now you can write on your external SD card again


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